（内消旋-5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四碳-4,11-二烯）镍（II）双-[O,O'-双（4-甲基苯基）二硫代磷酸酯]
(meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra-azacyclo-tetra-deca-4,11-diene)nickel(II) bis-[O,O'-bis(4-methyl-phen-yl) dithio-phosphate].
作者信息
Xie Bin, Xiang Yang-Guang, Zou Li-Ke, Chang Xiu-Li, Ji Chang-You
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1053. doi: 10.1107/S1600536809030955.
In the title compound, Ni(C(16)H(32)N(4))(2) or [Ni(trans[14]dien)]S(2)P(OC(6)H(4)Me-4)(2), where trans[14]dien is meso-5,7,7,12,14,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-deca-4,11-diene, the Ni(II) ion lies across a centre of inversion and is four-coordinated in a relatively undistorted square-planar arrangement by the four N atoms of the macrocyclic ligand trans[14]dien. The two O,O'-di(4-methyl-phen-yl)dithio-phos-phates act as counter-ions to balance the charge. Important geometric data include Ni-N = 1.9135 (16) and 1.9364 (15) Å.
在标题化合物Ni(C₁₆H₃₂N₄)₂或[Ni(trans[14]dien)][S₂P(OC₆H₄Me - 4)₂]₂中，其中trans[14]dien是内消旋-5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四碳-4,11-二烯，Ni(II)离子位于一个对称中心上，并通过大环配体trans[14]dien的四个N原子以相对未扭曲的平面正方形排列方式进行四配位。两个O,O'-二(4-甲基苯基)二硫代磷酸根作为抗衡离子来平衡电荷。重要的几何数据包括Ni-N = 1.9135 (16) 和1.9364 (15) Å。
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