Sahraei Atefeh, Kargar Hadi, Kia Reza, Tahir Muhammad Nawaz
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 15;67(Pt 1):m82-3. doi: 10.1107/S1600536810051834.
In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol-ecules are connected through inter-molecular C-H⋯O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by inter-molecular π-π inter-actions, with centroid-centroid distances in the range 3.3760 (15)-3.7196 (17) Å.
在席夫碱配合物[Ni(C₂₄H₂₂N₂O₄)]的标题中,Ni(II)原子呈现出平面正方形几何构型。中心苯环与两个外环之间的二面角分别为4.79 (15)°和7.54 (15)°。在晶体中,分子通过分子间C-H⋯O氢键相连,形成沿c轴延伸的链。晶体结构通过分子间的π-π相互作用进一步稳定,质心间距在3.3760 (15)-3.7196 (17) Å范围内。