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5-[(E)-2-Fluoro-benzyl-idene]-8-(2-fluoro-phen-yl)-2-hy-droxy-10-methyl-3,10-di-aza-hexa-cyclo-[10.7.1.1.0.0.0]henicosa-1(20),12,14,16,18-pentaen-6-one.

作者信息

Kumar Raju Suresh, Osman Hasnah, Yeap Chin Sing, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):o211-2. doi: 10.1107/S1600536810052815.

Abstract

In the title compound, C(33)H(26)F(2)N(2)O(2), the piperidone ring adopts a half-chair conformation and the pyrrolidine rings adopt half-chair and envelope conformations. The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydro-acenaphthyl-ene unit. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular structure. In the crystal, inter-molecular C-H⋯F hydrogen bonds link the mol-ecules into [010] chains. Weak C-H⋯π inter-actions are also observed.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/09f3/3050149/71e6c730b31f/e-67-0o211-fig1.jpg

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