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链状聚[[三甲基锡(IV)]-μ-苯基-亚硒酸根合-κO:O']

catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

作者信息

Guo Mengjie, Ru Jing, Zhang Rufen

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):m152. doi: 10.1107/S1600536810054243.

DOI:10.1107/S1600536810054243
PMID:21522835
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051585/
Abstract

In the title polymeric coordination compound, Sn(CH(3))(3)(C(6)H(5)O(2)Se), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

摘要

在标题聚合物配位化合物[Sn(CH₃)₃(C₆H₅O₂Se)]ₙ中，Sn(IV)原子具有扭曲的三角双锥几何构型，两个对称相关的桥连苯亚硒酸根阴离子的O原子处于轴向位置，三个甲基处于赤道位置。在晶体中，该配合物呈现出平行于b轴的链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f479/3051585/6bf3b8bb14ad/e-67-0m152-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f479/3051585/876f6e48945b/e-67-0m152-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f479/3051585/6bf3b8bb14ad/e-67-0m152-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f479/3051585/876f6e48945b/e-67-0m152-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f479/3051585/6bf3b8bb14ad/e-67-0m152-fig2.jpg

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引用本文的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.