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链状聚[[三甲基锡(IV)]-μ-(1,1'-联萘-2,2'-二基膦酸酯)]

catena-Poly[[trimethyl-tin(IV)]-μ-(1,1'-binaphthyl-2,2'-diyl phospho-nato)].

作者信息

Wu Jianjun, Zhang Rufen

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China .

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m63. doi: 10.1107/S160053680905291X.

DOI:10.1107/S160053680905291X
PMID:21579958
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980144/
Abstract

In the title polymeric coordination compound, Sn(CH(3))(3)(C(20)H(12)O(4)P), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the phosphate O atoms of the 1,1'-binaphthyl-2,2'-diyl phospho-nate ligands in axial positions and equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 1,1'-binaphthyl-2,2'-diyl phospho-nate ligand, forming a one-dimensional chain structure parallel to the b axis.

摘要

在标题聚合物配位化合物Sn(CH(3))(3)(C(20)H(12)O(4)P)中，Sn原子呈现出扭曲的三角双锥配位几何构型，其中1,1'-联萘-2,2'-二基膦酸酯配体的磷酸O原子处于轴向位置，三个甲基占据赤道位置。相邻的Sn原子通过与每个1,1'-联萘-2,2'-二基膦酸酯配体的两个O原子配位而桥连，形成平行于b轴的一维链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e15/2980144/abd6df1f04c8/e-66-00m63-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e15/2980144/44309a96cf38/e-66-00m63-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e15/2980144/abd6df1f04c8/e-66-00m63-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e15/2980144/44309a96cf38/e-66-00m63-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e15/2980144/abd6df1f04c8/e-66-00m63-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.