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利用顶空固相微萃取法分析 9 个西班牙石榴品种的挥发性成分。

Volatile composition of pomegranates from 9 Spanish cultivars using headspace solid phase microextraction.

机构信息

Univ. Miguel Hernández, Dept. de Producción Vegetal y Microbiología, Grupo de Fruticultura y Técnicas de Producción, Carretera de Beniel, km 3,2, 03312-Orihuela, Alicante, Spain.

出版信息

J Food Sci. 2011 Jan-Feb;76(1):S114-20. doi: 10.1111/j.1750-3841.2010.01945.x. Epub 2011 Jan 6.

Abstract

Fruits of 9 Spanish pomegranate cultivars were analyzed for quality parameters, volatile composition, and sensory profile. Volatile compounds were extracted using headspace solid phase micro-extraction (HS-SPME) and analyzed by gas chromatography-mass spectrometry (GC-MS) and flame ionization detector (GC-FID). Twenty-one compounds were found in the headspace of fresh pomegranate juices, including aldehydes, monoterpenes, and alcohols. The most abundant compounds were hexanal, limonene, trans-2-hexenal, and cis-3-hexenol. Fruits from the cultivars Mollar Elche(ME) ME14, ME1, and ME2 presented the highest values of overall liking by the consumer panel; however, their total volatiles concentration were low compared to the other pomegranate cultivars and their color intensity was intermediate. Overall consumer liking of pomegranate juices was mainly associated with the presence of monoterpenes (α-terpineol); however, high aldehydes (trans-2-hexenal) concentrations were correlated with poor overall consumer liking. Fruits from sour-sweet cultivars (PTO7 and ADO4) could improve the quality of ME pomegranate juices due to their intense color, high monoterpenes concentrations, and their moderate sourness. Practical Application: The information provided in this study proves that sour-sweet pomegranate fruits can be used in the manufacturing of pomegranate juices and will improve the sensory quality and the volatile composition of this product.

摘要

对 9 种西班牙石榴品种的果实进行了品质参数、挥发性成分和感官特性分析。采用顶空固相微萃取(HS-SPME)提取挥发性化合物,并用气相色谱-质谱联用(GC-MS)和火焰离子化检测器(GC-FID)进行分析。在新鲜石榴汁的顶空中共发现 21 种化合物,包括醛类、单萜和醇类。最丰富的化合物是己醛、柠檬烯、反式-2-己烯醛和顺式-3-己烯醇。品种 Mollar Elche(ME)ME14、ME1 和 ME2 的果实最受消费者喜爱;然而,与其他石榴品种相比,它们的总挥发性浓度较低,颜色强度中等。消费者对石榴汁的总体喜好主要与单萜(α-松油醇)的存在有关;然而,高浓度的醛(反式-2-己烯醛)与较差的总体消费者喜好有关。酸甜品种(PTO7 和 ADO4)的果实可改善 ME 石榴汁的品质,因为它们的颜色鲜艳、单萜浓度高,而且酸度适中。实际应用:本研究提供的信息证明,酸甜石榴果实可用于石榴汁的生产,将改善该产品的感官质量和挥发性成分。

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