超分子光催化：葫芦[8]脲催化 6-甲基香豆素光二聚反应的研究。
Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin.
机构信息
Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108-6050, USA.
出版信息
Chem Commun (Camb). 2011 Jun 14;47(22):6323-5. doi: 10.1039/c1cc11164g. Epub 2011 May 4.
PMID:21541417
Abstract
Guest induced shape change of the cucurbit[8]uril cavity is likely rate limiting in the supramolecular photocatalytic cycle for CB8 mediated photodimerization of 6-methylcoumarin.
摘要
客体诱导葫芦[8]脲空腔的形状变化可能是 CB8 介导的 6-甲基香豆素光二聚反应的超分子光催化循环中的速率限制步骤。
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