B-裂环型柠檬苦素骨架的合成。
Synthesis of the B-seco limonoid scaffold.
机构信息
Max-Planck-Institut für molekulare Physiologie, Chemische Biologie, Otto-Hahn-Str. 11, D-44227 Dortmund, Germany.
出版信息
Chem Commun (Camb). 2011 Jun 21;47(23):6545-7. doi: 10.1039/c1cc11388g. Epub 2011 May 9.
PMID:21552600
Abstract
The underlying stereochemically complex and densely functionalized scaffold of the B-seco limonoids was synthesized employing an Ireland-Claisen rearrangement as key transformation.
摘要
采用 Ireland-Claisen 重排作为关键转化，合成了具有复杂立体化学和密集官能团的 B-裂环二萜骨架。
相似文献
1
Synthesis of the B-seco limonoid scaffold.B-裂环型柠檬苦素骨架的合成。
Chem Commun (Camb). 2011 Jun 21;47(23):6545-7. doi: 10.1039/c1cc11388g. Epub 2011 May 9.
2
Simple enantioselective approach to synthetic limonoids.合成柠檬苦素的简单对映选择性方法。
J Am Chem Soc. 2008 May 28;130(21):6720-1. doi: 10.1021/ja802376g. Epub 2008 Apr 30.
3
Synthesis of the B-seco limonoid core scaffold.B-裂环柠檬苦素核心骨架的合成。
Beilstein J Org Chem. 2014 Jan 16;10:194-208. doi: 10.3762/bjoc.10.15. eCollection 2014.
4
A concise total synthesis of (±)-cipadonoid B from synthetic azedaralide.从合成的梓醇中简洁地全合成（±）-西柏洛因 B。
Chem Commun (Camb). 2011 Feb 28;47(8):2258-60. doi: 10.1039/c0cc04698a. Epub 2011 Jan 24.
5
A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group.一种具有角甲基的手性六氢薁骨架的新环扩张。
J Org Chem. 2011 Aug 19;76(16):6942-5. doi: 10.1021/jo201153h. Epub 2011 Jul 13.
6
Synthesis and cytotoxicity of novel isomeric C-seco limonoids.新型C-裂环柠檬苦素异构体的合成与细胞毒性
Eur J Med Chem. 2006 Aug;41(8):997-1002. doi: 10.1016/j.ejmech.2006.04.003. Epub 2006 Jun 19.
7
Synthesis of the BCDE molecular fragment of azadiradione mediated by titanocene(III).钛杂环戊二烯介导的瑞香素 BCDE 分子片段的合成。
J Org Chem. 2013 Oct 4;78(19):9571-8. doi: 10.1021/jo401646g. Epub 2013 Sep 23.
8
Progress Toward the Asymmetric De Novo Synthesis of Limonoids.向非对映从头合成柠檬苦素迈进。
Org Lett. 2024 Feb 9;26(5):1073-1077. doi: 10.1021/acs.orglett.3c04306. Epub 2024 Jan 26.
9
Total synthesis of azadirachtin--finally completed after 22 years.印楝素的全合成——历经22年终于完成。
Angew Chem Int Ed Engl. 2008;47(1):34-7. doi: 10.1002/anie.200703814.
10
Studies aimed at the total synthesis of azadirachtin. A modeled connection of C-8 and C-14 in azadirachtin.旨在进行印楝素全合成的研究。印楝素中C-8和C-14的模型连接。
Org Lett. 2002 Aug 22;4(17):2877-80. doi: 10.1021/ol026260y.
引用本文的文献
1
Chemical and chemoenzymatic routes to bridged homoarabinofuranosylpyrimidines: Bicyclic AZT analogues.桥连高阿拉伯呋喃糖基嘧啶的化学合成及化学酶促合成路线：双环齐多夫定类似物
Beilstein J Org Chem. 2022 Jan 11;18:95-101. doi: 10.3762/bjoc.18.10. eCollection 2022.
2
Assembly of the Limonoid Architecture by a Divergent Approach: Total Synthesis of (±)-Andirolide N via (±)-8α-Hydroxycarapin.通过发散途径构建柠檬苦素骨架：（±）-8α-羟基卡波林合成（±）-安蒂罗勒内酯 N 的全合成。
J Am Chem Soc. 2017 Jan 18;139(2):631-634. doi: 10.1021/jacs.6b12268. Epub 2017 Jan 5.
3
Synthesis of the B-seco limonoid core scaffold.B-裂环柠檬苦素核心骨架的合成。
Beilstein J Org Chem. 2014 Jan 16;10:194-208. doi: 10.3762/bjoc.10.15. eCollection 2014.
Zotero 插件