Fe2O3 负载纳米金催化的硝基芳烃和醇一锅法合成 N-烷基化苯胺。
Fe2O3-supported nano-gold catalyzed one-pot synthesis of N-alkylated anilines from nitroarenes and alcohols.
机构信息
Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.
出版信息
Chem Commun (Camb). 2011 Jun 14;47(22):6476-8. doi: 10.1039/c1cc11057h. Epub 2011 May 10.
PMID:21556401
Abstract
Here, we show the one-step synthesis of N-alkylated anilines from nitrobenzenes and alcohols catalyzed by nano-gold catalyst. The yields to N-alkylated anilines were ∼90% under mild conditions. The mechanism of this reaction was explored. It shows promise for clean and simple synthesis of N-alkylated anilines.
摘要
在这里，我们展示了纳米金催化剂催化硝基苯和醇一步合成 N-烷基苯胺的方法。在温和条件下，N-烷基苯胺的产率约为 90%。我们还探讨了该反应的机理，该方法为清洁、简单地合成 N-烷基苯胺提供了可能。
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