Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA.
Chem Commun (Camb). 2011 Jun 21;47(23):6707-9. doi: 10.1039/c1cc10920k. Epub 2011 May 10.
Tandem Au(III)-catalyzed heterocyclization/Nazarov cyclizations leading to substituted carbocycle fused furans are described. An interesting dichotomy of reaction pathways as a function of solvent, confirmed by the isolation and trapping of reaction intermediates, provided a basis for computational studies that supported the experimental findings.
串联 Au(III)-催化杂环化/Nazarov 环化反应，生成取代的碳环稠合呋喃，本文对此进行了描述。通过分离和捕获反应中间体，证实了溶剂对反应途径的有趣二分法，这为支持实验结果的计算研究提供了基础。
