Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing, People's Republic of China.
Nanotechnology. 2011 Jul 1;22(26):265708. doi: 10.1088/0957-4484/22/26/265708. Epub 2011 May 17.
Visible light transparent, UV-shielding and superhydrophobic nanostructured coatings have been successfully fabricated through a facile layer-by-layer deposition of TiO(2) and SiO(2) nanoparticles. The coatings are composed of an underlying UV-shielding TiO(2) layer and a top fully covered protective SiO(2) layer. The resulting coatings can block 100% of UVB and UVC and almost 85% of UVA. The fabricated surfaces have contact angles exceeding 165° after coating with organic PTES (1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane) molecules. The transparent superhydrophobic surfaces exhibit extremely strong UV stability. All coatings retain the initial UV-shielding and superhydrophobic properties even after exposure to 275 nm UV light with a light intensity of 75 mW cm(-2) for 12 h.
通过简单的 TiO(2) 和 SiO(2) 纳米粒子逐层沉积,成功制备了可见光透明、防紫外线和超疏水的纳米结构涂层。该涂层由底层防紫外线 TiO(2) 层和顶部完全覆盖的保护性 SiO(2) 层组成。所得涂层可阻挡 100%的 UVB 和 UVC 以及近 85%的 UVA。经有机 PTES(1H,1H,2H,2H-全氟辛基三乙氧基硅烷)分子涂覆后,制得的表面接触角超过 165°。透明超疏水表面具有极强的耐紫外线稳定性。所有涂层即使在 275nm 紫外线照射下(强度为 75mW/cm(-2))暴露 12 小时后,仍保持初始的防紫外线和超疏水性能。