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具有防紫外线和超疏水性能的透明纳米结构涂层。

Transparent nanostructured coatings with UV-shielding and superhydrophobicity properties.

机构信息

Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing, People's Republic of China.

出版信息

Nanotechnology. 2011 Jul 1;22(26):265708. doi: 10.1088/0957-4484/22/26/265708. Epub 2011 May 17.

Abstract

Visible light transparent, UV-shielding and superhydrophobic nanostructured coatings have been successfully fabricated through a facile layer-by-layer deposition of TiO(2) and SiO(2) nanoparticles. The coatings are composed of an underlying UV-shielding TiO(2) layer and a top fully covered protective SiO(2) layer. The resulting coatings can block 100% of UVB and UVC and almost 85% of UVA. The fabricated surfaces have contact angles exceeding 165° after coating with organic PTES (1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane) molecules. The transparent superhydrophobic surfaces exhibit extremely strong UV stability. All coatings retain the initial UV-shielding and superhydrophobic properties even after exposure to 275 nm UV light with a light intensity of 75 mW cm(-2) for 12 h.

摘要

通过简单的 TiO(2) 和 SiO(2) 纳米粒子逐层沉积,成功制备了可见光透明、防紫外线和超疏水的纳米结构涂层。该涂层由底层防紫外线 TiO(2) 层和顶部完全覆盖的保护性 SiO(2) 层组成。所得涂层可阻挡 100%的 UVB 和 UVC 以及近 85%的 UVA。经有机 PTES(1H,1H,2H,2H-全氟辛基三乙氧基硅烷)分子涂覆后,制得的表面接触角超过 165°。透明超疏水表面具有极强的耐紫外线稳定性。所有涂层即使在 275nm 紫外线照射下(强度为 75mW/cm(-2))暴露 12 小时后,仍保持初始的防紫外线和超疏水性能。

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