二氟二氧化（1,10-菲咯啉）钼（VI）
Difluoridodioxido(1,10-phenanthroline)molybdenum(VI).
作者信息
Wang Wenju, Zhang Youdi, Jin Xiangjun, Du Xiguang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 19;65(Pt 9):m1094. doi: 10.1107/S1600536809031626.
The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa-hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C-H⋯O and C-H⋯F hydrogen-bonding contacts and π-π inter-actions [centroid-centroid distance = 3.662 (1) Å] connect the complex mol-ecules into a three-dimensional supra-molecular framework.
标题化合物[MoF₂O₂(C₁₂H₈N₂)]具有非晶体学镜面对称性。Mo(VI)原子呈现出扭曲的八面体环境，菲咯啉N原子和两个氧基团形成赤道平面，F原子占据顶端位置。弱的C—H⋯O和C—H⋯F氢键接触以及π—π相互作用[质心-质心距离 = 3.662 (1) Å]将配合物分子连接成三维超分子框架。
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