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2-羟基-亚氨基-N'-[1-(2-吡啶基)亚乙基]丙酰肼

2-Hydroxy-imino-N'-[1-(2-pyrid-yl)ethyl-idene]propanohydrazide.

作者信息

Moroz Yurii S, Konovalova Irina S, Iskenderov Turganbay S, Pavlova Svetlana V, Shishkin Oleg V

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 26;65(Pt 9):o2242. doi: 10.1107/S1600536809033352.

DOI:10.1107/S1600536809033352
PMID:21577640
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969988/
Abstract

The title compound, C(10)H(12)N(4)O(2), features an intra-molecular N-H⋯N hydrogen bond formed between the imine NH and oxime N atoms. The oxime group and the amide C=O bond are anti to each other. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds into supra-molecular zigzag chains along the c axis.

摘要

标题化合物C(10)H(12)N(4)O(2)的特征是在亚胺NH和肟N原子之间形成了分子内N-H⋯N氢键。肟基和酰胺C=O键彼此呈反式构型。在晶体中，分子通过O-H⋯O氢键沿c轴连接成超分子锯齿链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d4e/2969988/c37d2915c8ad/e-65-o2242-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d4e/2969988/38122c341974/e-65-o2242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d4e/2969988/c37d2915c8ad/e-65-o2242-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d4e/2969988/38122c341974/e-65-o2242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d4e/2969988/c37d2915c8ad/e-65-o2242-fig2.jpg

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本文引用的文献

1
Dichlorido{2-hydroxy-imino-N'-[1-(2-pyrid-yl)ethyl-idene]propanohydrazide-κN,N',O}zinc(II) hemihydrate.二氯{2-羟基-亚氨基-N'-[1-(2-吡啶基)亚乙基]丙酰肼-κN,N',O}锌(II)半水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m353-4. doi: 10.1107/S160053680706535X.
2
Synthesis and structure of [2 x 2] molecular grid copper(II) and nickel(II) complexes with a new polydentate oxime-containing Schiff base ligand.含新型多齿肟基席夫碱配体的[2×2]分子网格铜（II）和镍（II）配合物的合成与结构
Inorg Chem. 2008 Jul 7;47(13):5656-65. doi: 10.1021/ic702375h. Epub 2008 May 24.
3
A short history of SHELX.
Bis{2-hydroxy-imino-N'-[1-(2-pyrid-yl)ethyl-idene]propanohydrazidato}zinc(II) dihydrate.
二水合双{2-羟基-亚氨基-N'-[1-(2-吡啶基)亚乙基]丙酰肼基}锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m242-3. doi: 10.1107/S1600536810003351.
4
(2E)-2-Hydroxy-imino-N'-[(E)-2-pyridyl-methyl-ene]propanohydrazide.（2E）-2-羟基-亚氨基-N'-[（E）-2-吡啶基亚甲基]丙酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 9;65(Pt 10):o2413. doi: 10.1107/S1600536809034400.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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On/off regulation of catalysis by allosteric control of metal complex nuclearity.
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