Liu Jian-Feng, Liu Jia-Lu, Zhao Guo-Liang
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1269-70. doi: 10.1107/S1600536809038823.
The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenol (HL) ligands, three independent thio-cyanate anions and an uncoordinated water mol-ecule. The Pr(III) ion is nine-coordinated. The thio-cyanate anions coordinate to the Pr(III) ion via the N atoms and the three HL ligands chelate the Pr(III) ion via the phenoxy and meth-oxy O atoms. The protonated imine N atoms are involved in intra-molecular hydrogen bonds with the phenolate groups.
标题化合物[Pr(NCS)₃(C₁₅H₁₅NO₂)₃]·H₂O的不对称单元由三个席夫碱2-甲氧基-6-[(4-甲基苯基)亚氨基甲基]苯酚（HL）配体、三个独立的硫氰酸根阴离子和一个未配位的水分子组成。Pr(III)离子为九配位。硫氰酸根阴离子通过N原子与Pr(III)离子配位，三个HL配体通过苯氧基和甲氧基O原子与Pr(III)离子螯合。质子化的亚胺N原子参与与酚盐基团的分子内氢键。
