catena-Poly[[di-μ-chlorido-bis-{[6-methoxy-2-(4-methyl-phenyl-iminio-methyl)phenolato-κO,O']cadmium(II)}]-di-μ(2)-thio-cyanato-κN:S;κS:N].
作者信息
Li Hua-Qiong, Xian Hui-Duo, Liu Jian-Feng, Zhao Guo-Liang
机构信息
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1593-4. doi: 10.1107/S1600536808038099.
The asymmetric unit of the title compound, Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2), contains the Schiff base 2-[(4-methyl-phenyl-imino)meth-yl]-6-methoxy-phenol (HL) ligand, one thio-cyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thio-cyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thio-cyanate (SCN) S atom, one isothio-cyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation.
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