Bis(2-imino-methyl-5-methoxy-phenolato)nickel(II).
作者信息
Tang Chunbao
机构信息
Department of Chemistry, Jiaying University, Meizhou 514015, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1275. doi: 10.1107/S1600536809039233.
Abstract
The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H⋯O hydrogen bonds.
摘要
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