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双（2-亚氨基甲基-5-甲氧基苯酚根）镍（II）

Bis(2-imino-methyl-5-methoxy-phenolato)nickel(II).

作者信息

Tang Chunbao

机构信息

Department of Chemistry, Jiaying University, Meizhou 514015, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1275. doi: 10.1107/S1600536809039233.

DOI:10.1107/S1600536809039233
PMID:21578047
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971283/
Abstract

The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H⋯O hydrogen bonds.

摘要

标题化合物[Ni(C₈H₈NO₂)₂]是一种中心对称的单核镍(II)配合物。位于对称中心的Ni(II)离子通过来自两个对称相关的2-亚氨基甲基-5-甲氧基苯酚盐配体的两个酚氧原子和两个亚胺氮原子以平面正方形几何构型进行四配位。在晶体中，分子通过N—H⋯O氢键连接成平行于(100)的波纹层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecac/2971283/df59ef0252a6/e-65-m1275-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecac/2971283/dfccae3ece45/e-65-m1275-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecac/2971283/df59ef0252a6/e-65-m1275-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecac/2971283/dfccae3ece45/e-65-m1275-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecac/2971283/df59ef0252a6/e-65-m1275-fig2.jpg

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