Liu Lin
College of Chemistry and Biology Engineering, Yichun University, Yichun 336000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 23;66(Pt 2):m195. doi: 10.1107/S1600536810002357.
In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra-hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio-cyanate ligand. In the crystal structure, centrosymmetrically related mol-ecules are linked into dimers through inter-molecular N-H⋯O hydrogen bonds. These dimers are further connected by inter-molecular C-H⋯S hydrogen bonds, forming chains running parallel to [101].
在标题单核镍(II)配合物[Ni(C₁₂H₁₇N₂O₂)(NCS)]中,金属原子通过席夫碱配体的酚氧原子、亚胺氮原子和胺氮原子以及硫氰酸根配体的氮原子以四面体畸变的平面正方形几何构型进行四配位。在晶体结构中,中心对称相关的分子通过分子间N-H⋯O氢键连接成二聚体。这些二聚体通过分子间C-H⋯S氢键进一步连接,形成平行于[101]的链。