• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{μ-双(1-甲基-咪唑-2-基)甲烷-κN:N}双-{[(1-甲基-咪唑-2-基)甲烷-κN,N]铜(I)} 双-(三氟甲烷磺酸酯)

{μ-Bis(1-methyl-imidazol-2-yl)methane-κN:N}bis-{[(1-methyl-imidazol-2-yl)methane-κN,N]copper(I)} bis-(tri-fluoro-methane-sulfonate).

作者信息

Matsumoto Jun, Kajita Yuji, Masuda Hideki

机构信息

Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1286-7. doi: 10.1107/S1600536809039622.

DOI:10.1107/S1600536809039622
PMID:21578056
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971412/
Abstract

The title compound, Cu(2)(C(9)H(12)N(4))(3)(2), contains two Cu(I) ions, three bis-(1-methyl-imidazol-2-yl)methane (Me(2)BIM) ligands, and two trifluoromethanesulfonate anions in the asymmetric unit. Each Cu(I) ion has a distorted trigonal-planar geometry and is coordinated by two N atoms from the Me(2)BIM ligand and another N atom from the Me(2)BIM that acts as a bridging ligand, another N atom of the bridging Me(2)BIM being linked to the second Cu(I) ion. The imidazole rings of Me(2)BIM form intra-molecular π-π stacking inter-actions [centroid-centroid distances = 3.445 (2) and 3.547 (2) Å].

摘要

标题化合物Cu₂(C₉H₁₂N₄)₃₂的不对称单元中包含两个Cu(I)离子、三个双(1-甲基咪唑-2-基)甲烷(Me₂BIM)配体和两个三氟甲磺酸根阴离子。每个Cu(I)离子具有扭曲的三角平面几何构型，由来自Me₂BIM配体的两个N原子和来自作为桥联配体的Me₂BIM的另一个N原子配位，桥联Me₂BIM的另一个N原子与第二个Cu(I)离子相连。Me₂BIM的咪唑环形成分子内π-π堆积相互作用[质心-质心距离 = 3.445 (2) 和3.547 (2) Å]。

相似文献

1
{μ-Bis(1-methyl-imidazol-2-yl)methane-κN:N}bis-{[(1-methyl-imidazol-2-yl)methane-κN,N]copper(I)} bis-(tri-fluoro-methane-sulfonate).{μ-双(1-甲基-咪唑-2-基)甲烷-κN:N}双-{[(1-甲基-咪唑-2-基)甲烷-κN,N]铜(I)} 双-(三氟甲烷磺酸酯)
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1286-7. doi: 10.1107/S1600536809039622.
2
[μ-1,2-Bis(4-pyrid-yl)ethane-κN:N']bis-[(4'-phenyl-2,2':6',2''-terpyridine-κN,N',N'')silver(I)] bis-(trifluoro-methane-sulfonate).[μ-1,2-双(4-吡啶基)乙烷-κN:N']双-[(4'-苯基-2,2':6',2''-三联吡啶-κN,N',N'')银(I)]双(三氟甲磺酸酯)
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1117-8. doi: 10.1107/S1600536810031776.
3
Bis[μ-4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine-κN]bis-[(trifluoro-methanesulfonato-κO)silver(I)].双[μ-4-甲基-2-(2-吡啶基-甲基-硫烷基)嘧啶-κN]双[(三氟甲磺酸根-κO)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1496. doi: 10.1107/S1600536810043631.
4
Bis[μ-1,2-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N]disilver(I) 3-carboxyl-ato-4-hydroxy-benzene-sulfonate methanol solvate trihydrate.双[μ-1,2-双-(1H-咪唑-1-基甲基)苯-κN:N]二银(I) 3-羧基-4-羟基苯磺酸盐甲醇溶剂合物三水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1042-3. doi: 10.1107/S1600536809030268.
5
Di-μ-chlorido-bis-[(2,2':6',2''-terpyridine-κ ,','')copper(II)] bis-(tri-fluoro-methane-sulfonate).二-μ-氯-双-[(2,2':6',2''-三联吡啶-κ ,','')铜(II)] 双-(三氟甲磺酸盐)
IUCrdata. 2021 Oct 21;6(Pt 10):x211096. doi: 10.1107/S2414314621010968. eCollection 2021 Oct.
6
Bis(μ-1,2-bis-{[2-(2-pyrid-yl)-1H-imidazol-1-yl]meth-yl}benzene)bis-[bis-(thio-cyanato-κN)cadmium(II)].
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):m378-9. doi: 10.1107/S1600536810008135.
7
Chlorido-(2,2'-{[2-(1-methyl-1-imidazol-2-yl-κ )imidazolidine-1,3-diyl-κ]bis-(methyl-ene)}bis-(1-methyl-1-imidazole-κ ))copper(II) perchlorate.高氯酸氯代 -（2,2'-{[2 -（1 - 甲基 - 1 - 咪唑 - 2 - 基 - κ）咪唑烷 - 1,3 - 二基 - κ]双 -（亚甲基）}双 -（1 - 甲基 - 1 - 咪唑 - κ））铜（II）
Acta Crystallogr E Crystallogr Commun. 2019 Apr 2;75(Pt 5):547-551. doi: 10.1107/S2056989019004055. eCollection 2019 May 1.
8
catena-Poly[[[bis-(thio-cyanato-κN)zinc(II)]-μ-1,2-bis-{[2-(2-pyrid-yl)-1H-imidazol-1-yl]meth-yl}benzene] 0.28-hydrate].链状聚[[[双（硫氰酸根合-κN）锌（II）]-μ-1,2-双-{[2-（2-吡啶基）-1H-咪唑-1-基]甲基}苯]0.28水合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m943-4. doi: 10.1107/S1600536810027571.
9
Poly[[bis-[μ(2)-N,N'-bis-(2-pyridyl-meth-yl)oxalamide-κN,O:N',O'][μ(2)-N,N'-bis-(2-pyridyl-meth-yl)oxalamide-κN:N']disilver(I)] bis-(trifluoro-methane-sulfonate)].聚[[双-[μ(2)-N,N'-双-(2-吡啶基甲基)草酰胺-κN,O:N',O'][μ(2)-N,N'-双-(2-吡啶基甲基)草酰胺-κN:N']二银(I)]双-(三氟甲磺酸酯)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):m1167-8. doi: 10.1107/S1600536810033611.
10
{μ-trans-N,N'-Bis[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine-κP:P'}bis-{(acetonitrile-κN)[dipyrido[3,2-a:2',3'-c]phenazine-κN,N]copper(I)} bis-(tetra-fluoridoborate).{μ-反式-N,N'-双[(二苯基膦基)甲基]苯-1,4-二胺-κP:P'}双{(乙腈-κN)[二吡啶并[3,2-a:2',3'-c]吩嗪-κN,N]铜(I)}双(四氟硼酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 19;65(Pt 9):m1085. doi: 10.1107/S1600536809031754.

本文引用的文献

1
Weakly coordinating counter-ions for highly efficient catalysis of intramolecular hydroamination.用于高效催化分子内氢胺化反应的弱配位抗衡离子
Dalton Trans. 2009 Jan 28(4):634-42. doi: 10.1039/b814168a.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Crystallographic, Electrochemical, and Pulsed EPR Study of Copper(II) Polyimidazole Complexes Relevant to the Metal Sites of Copper Proteins(,).与铜蛋白金属位点相关的铜（II）聚咪唑配合物的晶体学、电化学和脉冲电子顺磁共振研究（，）。
Inorg Chem. 1998 Aug 10;37(16):4030-4039. doi: 10.1021/ic9715660.