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双[μ-4-甲基-2-(2-吡啶基-甲基-硫烷基)嘧啶-κN]双[(三氟甲磺酸根-κO)银(I)]

Bis[μ-4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine-κN]bis-[(trifluoro-methanesulfonato-κO)silver(I)].

作者信息

Wang Huan-Huan, Zhang Chao-Yan, Cui Yue, Gao Qian, Xie Ya-Bo

机构信息

College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1496. doi: 10.1107/S1600536810043631.

DOI:10.1107/S1600536810043631
PMID:21588909
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009204/
Abstract

In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine ligands and one O atom from a trifluoro-methane-sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π-π inter-actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.

摘要

在中心对称的双核标题配合物[Ag₂(CF₃SO₃)₂(C₁₁H₁₁N₃S)₂]中，Ag(I)原子由两个4-甲基-2-(2-吡啶基-甲基-硫烷基)嘧啶配体的两个N原子和一个三氟甲磺酸根阴离子的一个O原子配位，形成扭曲的T型配位几何构型。配体通过一个吡啶基N原子和一个嘧啶基N原子采用双齿桥连配位模式。在晶体结构中，相邻嘧啶环之间存在π-π相互作用，质心到质心距离为3.875 (7) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/99a6/3009204/88eadcaf32ef/e-66-m1496-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/99a6/3009204/88eadcaf32ef/e-66-m1496-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/99a6/3009204/88eadcaf32ef/e-66-m1496-fig1.jpg

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