羰基[4-(2,3-二甲基苯基氨基)戊-3-烯-2-酮酸根-κN,O](三苯基膦-κP)铑(I)
Carbon-yl[4-(2,3-dimethyl-phenyl-amino)pent-3-en-2-onato-κN,O](triphenyl-phosphine-κP)rhodium(I).
作者信息
Venter Gertruida J S, Steyl Gideon, Roodt Andreas
机构信息
Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1321-2. doi: 10.1107/S1600536809039816.
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra-molecular hydrogen bonding is observed between a C-H group of the triphenyl-phosphine unit and the O atom of the enamino-ketonate ligand.
在标题化合物[Rh(C₁₃H₁₆NO)(C₁₈H₁₅P)(CO)]中，Rh(I)原子的配位几何构型为平面正方形，由双齿烯胺酮配体的配位N和O原子、羰基的一个C原子以及三苯基膦的一个P原子构成。该配合物中，单阴离子N,O-双齿配体的苯基单元存在0.591 (3):0.409 (3)的比例无序。在三苯基膦单元的一个C—H基团与烯胺酮配体的O原子之间观察到分子内氢键。
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