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叠氮基 -（苯甲腈 -κN）[氢 - 三（吡唑 -1-基 -κN）硼酸盐]（三苯基膦 -κP）钌（II）

Azido-(benzonitrile-κN)[hydrido-tris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).

作者信息

Huang Chiung-Cheng, Chen Han-Gung, Lo Yih Hsing, Lai Wen-Rong, Lin Chia-Her

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):m864. doi: 10.1107/S1600536810021513.

DOI:10.1107/S1600536810021513
PMID:21587768
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3006820/
Abstract

Facile ligand substitution is observed when the ruthenium-azide complex, [RuN(3)(Tp)(PPh(3))(2)] [Tp,HB(pz)(3), pz = pyrazol-yl, PPh(3) = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C(9)H(10)BN(6))(N(3))(C(7)H(5)N)(C(18)H(15)P)]. The asymmetric unit contains two crystallographically independent mol-ecules. In each one, the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.

摘要

当叠氮化钌配合物[RuN(3)(Tp)(PPh(3))(2)] [Tp，HB(pz)(3)，pz = 吡唑基，PPh(3) = 三苯基膦] 与苯甲腈反应时，可观察到容易的配体取代反应，生成标题化合物[Ru(C(9)H(10)BN(6))(N(3))(C(7)H(5)N)(C(18)H(15)P)]。不对称单元包含两个晶体学独立的分子。在每个分子中，Ru(II) 原子由来自一个htpb配体、一个叠氮配体和一个苯甲腈配体的五个N原子以及来自一个三苯基膦 (tpp) 配体的一个P原子以扭曲的八面体几何构型进行六配位。叠氮基团几乎呈线性，以平均Ru-N-N角124.9 (3)°与Ru配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/095c/3006820/5afc7e1a0b8a/e-66-0m864-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/095c/3006820/5afc7e1a0b8a/e-66-0m864-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/095c/3006820/5afc7e1a0b8a/e-66-0m864-fig1.jpg

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Multiple mixed-valence behavior in trans,trans-[(tpy)(Cl)2Os(III)(mu-1,3-N3)Os(III)(Cl)2(tpy)]+. An azido bridge from the reaction between trans-[Os(VI)(tpy)(Cl)2(N)]+ and NH3.反式，反式-[(三联吡啶)(氯)₂锇(III)(μ-1,3-叠氮基)锇(III)(氯)₂(三联吡啶)]⁺中的多重混合价态行为。反式-[锇(VI)(三联吡啶)(氯)₂(N)]⁺与NH₃反应生成的叠氮基桥。
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