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trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-κP]dichloridopalladium(II).

作者信息

van Blerk Charmaine, Holzapfel Cedric W

机构信息

University of Johannesburg, Department of Chemistry, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1341. doi: 10.1107/S1600536809040744.

DOI:10.1107/S1600536809040744
PMID:21578097
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971441/
Abstract

The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)PdPPh(PhOMe)(2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis-(2-methoxy-phen-yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.

摘要

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Aluminum triflate as a highly active and efficient nonprotic cocatalyst in the palladium-catalyzed methoxycarbonylation reaction.三氟甲磺酸铝作为钯催化甲氧羰基化反应中一种高活性且高效的非质子共催化剂。
Angew Chem Int Ed Engl. 2008;47(3):560-3. doi: 10.1002/anie.200702889.
3
Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines.
与乙烯和一氧化碳交替共聚以及烯烃的烷氧基羰基化相关的酰基钯（II）配合物的醇解反应：顺式配位膦的重要性
J Am Chem Soc. 2003 May 7;125(18):5523-39. doi: 10.1021/ja029341y.