van Blerk Charmaine, Holzapfel Cedric W
University of Johannesburg, Department of Chemistry, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1342. doi: 10.1107/S1600536809040719.
The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], shows a nearly square-planar geometry for the Pd(II) atom within the Cl(2)PdP(PhOMe)(3) ligand set. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one Pd(II) atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.
标题化合物[PdCl₂(C₂₁H₂₁O₃P)₂]的结构表明，在Cl₂Pd[P(PhOMe)₃]₂配体体系中，Pd(II)原子具有近似平面正方形的几何构型。Pd(II)原子位于对称中心上，因此不对称单元包含半个分子，即半个Pd(II)原子、一个Cl原子和一个三(2-甲氧基苯基)膦配体。
