de Souza Marcus V N, Tiekink Edward R T, Wardell James L, Wardell Solange M S V
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):o3120-1. doi: 10.1107/S160053680904834X.
In the title salt hydrate, C(11)H(12)ClN(2) (+)·Cl(-)·H(2)O, the quinolin-ium core is essentially planar (r.m.s. deviation = 0.027 Å) with the chloro-ethyl side chain being almost orthogonal to the core [C-N-C-C torsion angle = -80.0 (3)°]. In the crystal packing, the water mol-ecule bridges three species, forming donor inter-actions to two chloride anions and accepting a hydrogen bond from the quinolinium H atom. The chloride anion accepts a hydrogen bond from the amine N atom with the result that a two-dimensional supra-molecular array is formed in the ac plane. A C-H⋯Cl interaction also occurs.
在标题水合盐C(11)H(12)ClN(2)(+)·Cl(-)·H(2)O中，喹啉鎓核心基本呈平面状（均方根偏差 = 0.027 Å），氯乙基侧链与核心几乎正交 [C-N-C-C扭转角 = -80.0 (3)°]。在晶体堆积中，水分子连接三种物种，与两个氯离子形成供体相互作用，并接受来自喹啉鎓H原子的氢键。氯离子接受来自胺N原子的氢键，结果在ac平面上形成二维超分子阵列。还存在C-H⋯Cl相互作用。
