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3,3'-亚乙基双(3,4-二氢-6-氯-2H-1,3-苯并恶嗪)

3,3'-Ethyl-enebis(3,4-dihydro-6-chloro-2H-1,3-benzoxazine).

作者信息

Rivera Augusto, Rojas Jicli José, Ríos-Motta Jaime, Dušek Michal, Fejfarová Karla

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 21;66(Pt 5):o1134. doi: 10.1107/S1600536810014248.

DOI:10.1107/S1600536810014248
PMID:21579183
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979041/
Abstract

The asymmetric unit of the title compound, C(18)H(18)Cl(2)N(2)O(2), contains one half of an independent mol-ecule, the other half being generated via a centre of inversion at the mol-ecular centroid. In the crystal structure, mol-ecular chains are formed through non-classical C-H⋯ O hydrogen bonds between an axial H atom of the oxazine ring and the O atom of a neighbouring mol-ecule.

摘要

标题化合物C(18)H(18)Cl(2)N(2)O(2)的不对称单元包含一个独立分子的一半，另一半通过分子质心处的反演中心生成。在晶体结构中，分子链通过恶嗪环轴向H原子与相邻分子的O原子之间的非经典C-H⋯O氢键形成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/2979041/e15f38ee3832/e-66-o1134-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/2979041/5a4997da39f2/e-66-o1134-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/2979041/e15f38ee3832/e-66-o1134-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/2979041/5a4997da39f2/e-66-o1134-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/2979041/e15f38ee3832/e-66-o1134-fig2.jpg

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