• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

3,3'-（乙烷-1,2-二基）双-（6-甲基-3,4-二氢-2H-1,3-苯并恶嗪）

3,3'-(Ethane-1,2-di-yl)bis-(6-methyl-3,4-dihydro-2H-1,3-benzoxazine).

作者信息

Rivera Augusto, Camacho Jairo, Ríos-Motta Jaime, Pojarová Michaela, Dušek Michal

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2028. doi: 10.1107/S1600536811027139. Epub 2011 Jul 13.

DOI:10.1107/S1600536811027139
PMID:22091057
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3213478/
Abstract

The asymmetric unit of the title compound, C(20)H(24)N(2)O(2), contains one half-mol-ecule, which is completed by inversion symmetry. In the crystal, mol-ecular chains are formed through non-classical C-H⋯O hydrogen bonds, formed between axial H atoms of the oxazine ring and a O atom of a neighboring mol-ecule.

摘要

标题化合物C₂₀H₂₄N₂O₂的不对称单元包含半个分子，通过反演对称性形成完整分子。在晶体中，分子链通过非经典的C-H⋯O氢键形成，这些氢键是在恶嗪环的轴向H原子与相邻分子的一个O原子之间形成的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d39/3213478/a3d553e75dbc/e-67-o2028-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d39/3213478/57f41d42e313/e-67-o2028-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d39/3213478/a3d553e75dbc/e-67-o2028-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d39/3213478/57f41d42e313/e-67-o2028-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d39/3213478/a3d553e75dbc/e-67-o2028-fig2.jpg

相似文献

1
3,3'-(Ethane-1,2-di-yl)bis-(6-methyl-3,4-dihydro-2H-1,3-benzoxazine).3,3'-（乙烷-1,2-二基）双-（6-甲基-3,4-二氢-2H-1,3-苯并恶嗪）
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2028. doi: 10.1107/S1600536811027139. Epub 2011 Jul 13.
2
Crystal structure and C-H⋯F hydrogen bonding in the fluorinated bis-benzoxazine: 3,3'-(ethane-1,2-di-yl)bis-(6-fluoro-3,4-di-hydro-2-1,3-benzoxazine).氟化双苯并恶嗪：3,3'-(乙烷-1,2-二基)双-(6-氟-3,4-二氢-2H-1,3-苯并恶嗪)中的晶体结构和C-H⋯F氢键
Acta Crystallogr E Crystallogr Commun. 2016 Sep 30;72(Pt 10):1509-1511. doi: 10.1107/S2056989016015243. eCollection 2016 Oct 1.
3
3,3'-Ethyl-enebis(3,4-dihydro-6-chloro-2H-1,3-benzoxazine).3,3'-亚乙基双(3,4-二氢-6-氯-2H-1,3-苯并恶嗪)
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 21;66(Pt 5):o1134. doi: 10.1107/S1600536810014248.
4
3,3'-(Ethane-1,2-diyl)bis(6-meth-oxy-3,4-dihydro-2H-1,3-benzoxazine) mono-hydrate.3,3'-（乙烷-1,2-二基）双（6-甲氧基-3,4-二氢-2H-1,3-苯并恶嗪）一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2734. doi: 10.1107/S1600536812035519. Epub 2012 Aug 23.
5
3,3'-(Ethane-1,2-di-yl)bis-(3,4-dihydro-2H-1,3-benzoxazine).3,3'-（乙烷-1,2-二基）双-（3,4-二氢-2H-1,3-苯并恶嗪）
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o148. doi: 10.1107/S1600536811053530. Epub 2011 Dec 17.
6
Crystal structure of 1,2-bis-(6-bromo-3,4-dihydro-2-benz[][1,3]oxazin-3-yl)ethane: a bromine-containing bis-benzoxazine.1,2-双-(6-溴-3,4-二氢-2-苯并[][1,3]恶嗪-3-基)乙烷的晶体结构：一种含溴双苯并恶嗪
Acta Crystallogr E Crystallogr Commun. 2016 Oct 25;72(Pt 11):1645-1647. doi: 10.1107/S2056989016016509. eCollection 2016 Nov 1.
7
2,2'-Dihydroxy-N,N'-(ethane-1,2-di-yl)di-benzamide.2,2'-二羟基-N,N'-(乙烷-1,2-二基)二苯甲酰胺
Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):o201. doi: 10.1107/S1600536812051963. Epub 2013 Jan 9.
8
Bis(2,2'-bipyridine-κN,N')bis-(1H-indole-2-carboxyl-ato-κO,O')cadmium-2,2'-bipyridine-water (1/0.5/2).双（2,2'-联吡啶-κN,N'）双（1H-吲哚-2-羧酸根-κO,O'）镉-2,2'-联吡啶-水（1/0.5/2）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m879-80. doi: 10.1107/S1600536811021064. Epub 2011 Jun 11.
9
C-I⋯N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3'-(ethane-1,2-di-yl)bis-(6-iodo-3,4-di-hydro-2-1,3-benzoxazine).C-I⋯N短接触作为构建3,3'-(乙烷-1,2-二基)双-(6-碘-3,4-二氢-2H-1,3-苯并恶嗪)晶体结构中晶体堆积的工具。
Acta Crystallogr E Crystallogr Commun. 2017 Apr 7;73(Pt 5):664-666. doi: 10.1107/S2056989017005047. eCollection 2017 May 1.
10
tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl-ate.6-氨基-3,4-二氢-2H-1,4-苯并恶嗪-4-羧酸叔丁酯
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):o3269. doi: 10.1107/S160053681004777X.

引用本文的文献

1
C-I⋯N short contacts as tools for the construction of the crystal packing in the crystal structure of 3,3'-(ethane-1,2-di-yl)bis-(6-iodo-3,4-di-hydro-2-1,3-benzoxazine).C-I⋯N短接触作为构建3,3'-(乙烷-1,2-二基)双-(6-碘-3,4-二氢-2H-1,3-苯并恶嗪)晶体结构中晶体堆积的工具。
Acta Crystallogr E Crystallogr Commun. 2017 Apr 7;73(Pt 5):664-666. doi: 10.1107/S2056989017005047. eCollection 2017 May 1.
2
Crystal structure of 1,2-bis-(6-bromo-3,4-dihydro-2-benz[][1,3]oxazin-3-yl)ethane: a bromine-containing bis-benzoxazine.1,2-双-(6-溴-3,4-二氢-2-苯并[][1,3]恶嗪-3-基)乙烷的晶体结构：一种含溴双苯并恶嗪
Acta Crystallogr E Crystallogr Commun. 2016 Oct 25;72(Pt 11):1645-1647. doi: 10.1107/S2056989016016509. eCollection 2016 Nov 1.
3

本文引用的文献

1
3,3'-Ethyl-enebis(3,4-dihydro-6-chloro-2H-1,3-benzoxazine).3,3'-亚乙基双(3,4-二氢-6-氯-2H-1,3-苯并恶嗪)
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 21;66(Pt 5):o1134. doi: 10.1107/S1600536810014248.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
IMIDAZOLIDINES. 3. 2-SUBSTITUTED 1,3-BIS-(O-HYDROXYBENZYL)-IMIDAZOLIDINES.
J Med Chem. 1963 Nov;6:701-5. doi: 10.1021/jm00342a016.
Crystal structure and C-H⋯F hydrogen bonding in the fluorinated bis-benzoxazine: 3,3'-(ethane-1,2-di-yl)bis-(6-fluoro-3,4-di-hydro-2-1,3-benzoxazine).氟化双苯并恶嗪：3,3'-(乙烷-1,2-二基)双-(6-氟-3,4-二氢-2H-1,3-苯并恶嗪)中的晶体结构和C-H⋯F氢键
Acta Crystallogr E Crystallogr Commun. 2016 Sep 30;72(Pt 10):1509-1511. doi: 10.1107/S2056989016015243. eCollection 2016 Oct 1.
4
3,3'-(Ethane-1,2-diyl)bis(6-meth-oxy-3,4-dihydro-2H-1,3-benzoxazine) mono-hydrate.3,3'-（乙烷-1,2-二基）双（6-甲氧基-3,4-二氢-2H-1,3-苯并恶嗪）一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2734. doi: 10.1107/S1600536812035519. Epub 2012 Aug 23.
5
3,3'-(Ethane-1,2-di-yl)bis-(3,4-dihydro-2H-1,3-benzoxazine).3,3'-（乙烷-1,2-二基）双-（3,4-二氢-2H-1,3-苯并恶嗪）
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o148. doi: 10.1107/S1600536811053530. Epub 2011 Dec 17.
4
Highly antibacterial active aminoacyl penicillin conjugates with acylated bis-catecholate siderophores based on secondary diamino acids and related compounds.基于仲二氨基酸和相关化合物的具有酰化双儿茶酚铁载体的高抗菌活性氨酰基青霉素缀合物。
J Med Chem. 2002 Jul 4;45(14):3032-40. doi: 10.1021/jm010546b.