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Hexaaqua-magnesium(II) bis-{[2-(1-phenyl-1H-tetra-zol-5-yl)sulfan-yl]acetate}.

作者信息

Fu Chun-Hua, Zhou Xiang, Yu Qing, Bian He-Dong

机构信息

College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, 541004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):m657. doi: 10.1107/S1600536810016983.

Abstract

The asymmetric unit of the title compound, Mg(H(2)O)(6)(2), contains one-half of a Mg(H(2)O)(6) cation ( symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetra-zol-5-yl)sulfan-yl]acetate anion. The Mg(II) cation is coordinated by six water mol-ecules, exhibiting a slightly distorted octa-hedral coordination. A two-dimensional network parallel to (001) is formed via extensive hydrogen-bonding inter-actions involving the water mol-ecules as donors and the tetra-zole N and carboxyl-ate O atoms of the anion as acceptors. The shortest distance between two adjacent parallel benzene rings is 3.315 (2) Å. The dihedral angle between the benzene ring and the tetra-zole ring is 40.98 (2)°.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7fca/2979576/db0533fbe9fc/e-66-0m657-fig1.jpg

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