Wang Hai-Rong, Li Guo-Ting
Department of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou, 450011, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1457. doi: 10.1107/S1600536811038918. Epub 2011 Sep 30.
In the title compound, [Fe(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)] or [Fe(POA)(2)(H(2)O)(4)], the Fe(II) atom is located on an inversion center and is ligated by four O atoms of coordinated water mol-ecules in the equatorial plane while two POA ligands acting as monodentate ligands occupy the axial positions through their pyridyl N atoms, completing a slightly distorted octa-hedral coordination geometry. A three-dimensional supra-molecular network is formed by multiple O-H⋯O hydrogen-bonding inter-actions between the coordinated water donors and the uncoordinated carboxyl acceptors.
在标题化合物[Fe(C₉H₆N₃O₃S)₂(H₂O)₄]或[Fe(POA)₂(H₂O)₄]中,Fe(II)原子位于一个对称中心上,在赤道平面上被配位水分子的四个O原子所配位,而两个作为单齿配体的POA配体通过其吡啶基N原子占据轴向位置,形成一个略微扭曲的八面体配位几何构型。通过配位水供体和未配位羧基受体之间的多个O-H⋯O氢键相互作用形成了一个三维超分子网络。