Yu Gui-Miao, Li Yun-Hui, Zou Li-Fei, Zhu Jian-Wei, Liu Xiao-Qiu
Acta Crystallogr Sect E Struct Rep Online. 2010 May 22;66(Pt 6):m693-4. doi: 10.1107/S1600536810018040.
In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa-hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by inter-molecular N-H⋯O hydrogen bonds. The dimers, perchlorate anions and methanol solvent mol-ecules are further connected into a chain along [01] through N-H⋯O and O-H⋯O hydrogen bonds.
在标题配合物[Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH中，两个锰(II)离子由来自两个配体的两个酚氧原子桥连，形成一个Mn(2)O(2)四边形。每个锰(II)离子具有扭曲的八面体配位几何构型。一个锰(II)离子由来自两个配体的两个N原子和四个O原子配位，另一个由来自三个配体的一个N原子和五个O原子配位。通过分子间N-H⋯O氢键形成二聚体。二聚体、高氯酸根阴离子和甲醇溶剂分子通过N-H⋯O和O-H⋯O氢键沿[01]进一步连接成链。
