一水合氯化双{2-[(2-苯甲酰基肼-1-基亚基)甲基]-6-甲氧基苯酚根合}铁(III)
Bis{2-[(2-benzoyl-hydrazin-1-yl-idene)meth-yl]-6-meth-oxy-phenolato}iron(III) chloride monohydrate.
作者信息
Zou Li-Fei, Ma Yu-Qin, Yu Gui-Miao, Gan Feng-Jiao, Li Yun-Hui
机构信息
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):m828. doi: 10.1107/S1600536810023226.
In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octa-hedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(-) anions and water mol-ecules are connected into a chain along [100] through N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds. Two adjacent chains are linked by O-H⋯O hydrogen bonds.
在标题单核铁（III）配合物[Fe(C₁₅H₁₃N₂O₃)₂]Cl·H₂O中，Fe(III)原子具有扭曲的八面体几何构型，由来自两个配体的四个O原子和两个N原子进行六配位。在晶体结构中，配合物阳离子、Cl⁻阴离子和水分子通过N—H⋯O、O—H⋯Cl和N—H⋯Cl氢键沿[100]方向连接成一条链。两条相邻的链通过O—H⋯O氢键相连。
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