（4'-烯丙氧基-2,2':6',2''-三联吡啶）（二苯甲酰甲烷基）二硝酸铒（III）乙腈溶剂合物
(4'-All-yloxy-2,2':6',2''-terpyridine)(dibenzoyl-methanido)dinitratoerbium(III) acetonitrile solvate.
作者信息
Mei Qunbo, Tong Bihai
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m106. doi: 10.1107/S1600536809055032.
Abstract
The title complex, [Er(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN, has been synthesized from 4'-all-yloxy-2,2':6',2''-terpyridine (altpy), dibenzoyl-methane and erbium nitrate. The distorted monocapped square anti-prismatic coordination polyhedron is formed by a bidentate dibenzoyl-methanide residue, a tridentate altpy ligand and two nitrate anions that act as bidentate ligands and occupy mutually trans sites.
摘要
标题配合物[Er(C₁₅H₁₁O₂)(NO₃)₂(C₁₈H₁₅N₃O)]·CH₃CN由4'-烯丙氧基-2,2':6',2''-三联吡啶（altpy）、二苯甲酰甲烷和硝酸铒合成。扭曲的单帽方反棱柱配位多面体由一个双齿二苯甲酰甲烷残基、一个三齿altpy配体和两个作为双齿配体并占据相互反位的硝酸根阴离子形成。
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