{μ - 6,6'-二甲氧基 - 2,2'-[丙烷 - 1,3 - 二基双(腈基亚甲基)]二酚根合}三硝酸铜(II)铒(III)丙酮溶剂化物
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)erbium(III) acetone solvate.
作者信息
Xing Jing-Chun, Bo Yu-Long, Zhang Bing, Li Wen-Zhi
机构信息
Department of Anesthesiology, The Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1299. doi: 10.1107/S1600536809037787.
Abstract
In the title complex, [CuEr(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is coordinated in a square-planar environment by two O atoms and two N atoms of a Schiff base ligand. The Er(III) ion is bis-chelated by three nitrate ligands and coordinated by four O atoms of the Schiff base ligand in a slightly distorted bicapped square-anti-prismatic environment.
摘要
在标题配合物[CuEr(C₁₉H₂₀N₂O₄)(NO₃)₃]·CH₃COCH₃中，Cu(II)离子通过席夫碱配体的两个O原子和两个N原子在平面正方形环境中配位。Er(III)离子被三个硝酸根配体双螯合，并在略微扭曲的双帽正方形反棱柱环境中通过席夫碱配体的四个O原子配位。
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本文引用的文献
1
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)europium(III).{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二基双(亚氨基甲基亚基)]二酚根合}三硝酸铜(II)铕(III)
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):m1206. doi: 10.1107/S1600536808026329.
2
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diyl-bis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)samarium(III) acetone solvate.{μ - 6,6'-二甲氧基 - 2,2'-[丙烷 - 1,3 - 二基 - 双(腈基亚甲基)] - 二苯酚根合}-三硝酸铜(II)钐(III)丙酮溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m344. doi: 10.1107/S1600536807061454.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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