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(μ-2,3-二羟基丁烷-1,4-二硫醇根)双[三苯基锡(IV)]

(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

作者信息

Li Cuiping, Zhang Rufen

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m112. doi: 10.1107/S1600536809055135.

Abstract

In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

摘要

在标题化合物[Sn₂(C₆H₅)₆(C₄H₈O₂S₂)]中,Sn原子周围的几何构型为扭曲的四面体。羟基参与O—H⋯O氢键作用,将分子连接成中心对称的二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ac6/2979966/58f7d8cf4d35/e-66-0m112-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

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