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双[μ-4-(4-羧基苯氧基)邻苯二甲酸根合]双[三水合镍(II)]

Bis[μ-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-nickel(II)].

作者信息

Cai Xue

机构信息

Department of Chemistry, Mudanjiang Normal College, Mudanjiang 157012, Heilongjiang Province, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m60. doi: 10.1107/S1600536810049718.

DOI:10.1107/S1600536810049718
PMID:21522579
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050356/
Abstract

In the centrosymmetric binuclear title compound, [Ni(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], the Ni(II) ion is in a distorted octa-hedral coordination geometry with O(6) donors, three from three water mol-ecules, the others from three carboxylate groups of two ligands. Extensive O-H⋯O hydrogen bonding connects the mol-ecules into a three-dimensional supra-molecular structure.

摘要

在中心对称的双核标题化合物[Ni₂(C₁₅H₈O₇)₂(H₂O)₆]中，Ni(II)离子处于扭曲的八面体配位几何构型，其配位原子为O原子，其中三个来自三个水分子，另外三个来自两个配体的三个羧酸根基团。广泛的O—H⋯O氢键将分子连接成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c48e/3050356/21e0083f87a8/e-67-00m60-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c48e/3050356/01dd70e59906/e-67-00m60-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c48e/3050356/21e0083f87a8/e-67-00m60-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c48e/3050356/01dd70e59906/e-67-00m60-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c48e/3050356/21e0083f87a8/e-67-00m60-fig2.jpg

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本文引用的文献

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Diaqua-bis(N,N-diethyl-nicotinamide-κN)bis-[4-(dimethyl-amino)benzoato-κO]nickel(II).
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):m1015-6. doi: 10.1107/S1600536809030098.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.