二氯[N,N-二乙基-N'-(2-吡啶基亚甲基)乙烷-1,2-二胺]汞(II)
Dichlorido[N,N-diethyl-N'-(2-pyridyl-methyl-ene)ethane-1,2-diamine]mercury(II).
作者信息
Kim Young-Inn, Seo Hoe-Joo, Kim Ji-Hoon, Lee You-Soon, Kang Sung Kwon
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m124. doi: 10.1107/S1600536810000103.
The Hg atom in the title compound, [HgCl(2)(C(12)H(19)N(3))], adopts a distorted trigonal-bipyramidal geometry, being ligated by two Cl atoms and three N atoms of the N,N-diethyl-N'-(2-pyridylmethyl-ene)ethane-1,2-diamine ligand. The dihedral angle between the HgN(3) and HgCl(2 )least-squares planes is 88.6 (1)°. The Hg-N distances including the pyridine N and the ammonium N atom are about 0.20 Å longer than the Hg-N distance including the imino N atom.
在标题化合物[HgCl₂(C₁₂H₁₉N₃)]中，汞（Hg）原子采用扭曲的三角双锥几何构型，由两个氯原子以及N,N - 二乙基 - N' - (2 - 吡啶基亚甲基)乙烷 - 1,2 - 二胺配体的三个氮原子配位。HgN₃和HgCl₂最小二乘平面之间的二面角为88.6 (1)°。包括吡啶氮和铵氮原子的Hg - N距离比包括亚氨基氮原子的Hg - N距离长约0.20 Å。
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