• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

二-μ-氯-双-{[2-(苄基亚氨基甲基)吡啶-κN,N']氯化汞(II)}二氯化汞(II)

Di-μ-chlorido-bis-{[2-(benzyl-imino-meth-yl)pyridine-κN,N']chloridomercury(II)} dichloridomercury(II).

作者信息

Kim Young-Inn, Song Young-Kwang, Yun Seong-Jae, Kim In-Chan, Kang Sung Kwon

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 8;67(Pt 1):m52-3. doi: 10.1107/S1600536810050725.

DOI:10.1107/S1600536810050725
PMID:21522571
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050237/
Abstract

The Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(13)H(12)N(2))(2)]·[HgCl(2)], adopts a distorted square-pyramidal geometry, being coordinated by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds [2.8428 (11) Å] is significantly longer than the other [2.5327 (10) Å]. In the crystal, there are weak π-π inter-actions [centroid-centroid distance = 3.630 (3) Å] between the aromatic rings of the discrete units. The HgCl(2) adduct molecule is located on an inversion centre and has an Hg-Cl bond length of 2.2875 (11) Å.

摘要

在标题中的中心对称双核配合物[Hg₂Cl₄(C₁₃H₁₂N₂)₂]·[HgCl₂]中，Hg(II)离子采用扭曲的四方锥几何构型，由双螯合的N-杂环配体、两个桥连Cl原子和一个端基Cl原子配位。其中一个桥连的Hg-Cl键[2.8428 (11) Å]明显长于另一个[2.5327 (10) Å]。在晶体中，离散单元的芳香环之间存在弱的π-π相互作用[质心-质心距离 = 3.630 (3) Å]。HgCl₂加合物分子位于一个对称中心上，Hg-Cl键长为2.2875 (11) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d596/3050237/ac3a28a82b55/e-67-00m52-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d596/3050237/ac3a28a82b55/e-67-00m52-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d596/3050237/ac3a28a82b55/e-67-00m52-fig1.jpg

相似文献

1
Di-μ-chlorido-bis-{[2-(benzyl-imino-meth-yl)pyridine-κN,N']chloridomercury(II)} dichloridomercury(II).二-μ-氯-双-{[2-(苄基亚氨基甲基)吡啶-κN,N']氯化汞(II)}二氯化汞(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 8;67(Pt 1):m52-3. doi: 10.1107/S1600536810050725.
2
Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II)).二-μ-氯-双-({2-[(4-溴-苯基)-亚氨基-甲基]吡啶-κN,N'}-氯化汞(II))
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m889. doi: 10.1107/S1600536809025641.
3
Di-μ-chlorido-bis-[(2-amino-4-methyl-pyridine-κN)-chloridomercury(II)].二-μ-氯-双-[(2-氨基-4-甲基吡啶-κN)-氯汞(II)]
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1300-1. doi: 10.1107/S1600536812039803. Epub 2012 Sep 26.
4
Di-μ-chlorido-bis-{chlorido[2,3-dimethyl-N-(pyridin-2-yl-methyl-idene)aniline-κ(2)N,N']mercury(II)}.二-μ-氯-双-{氯代[2,3-二甲基-N-(吡啶-2-基亚甲基)苯胺-κ(2)N,N']汞(II)}
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1294. doi: 10.1107/S1600536812039050. Epub 2012 Sep 22.
5
Di-μ-chlorido-bis-(chlorido{2-[(4-ethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II)).二-μ-氯代-双-(氯代{2-[(4-乙基-苯基)亚氨基-甲基]吡啶-κN,N'}铜(II))
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1296. doi: 10.1107/S1600536811032053. Epub 2011 Aug 27.
6
Di-μ-chlorido-bis-{chlorido[2-(2-furyl-methyl-imino-meth-yl)pyridine-κN,N']nickel(II)}.二-μ-氯代-双-{氯代[2-(2-呋喃基-甲基-亚氨基-甲基)吡啶-κN,N']镍(II)}
Acta Crystallogr Sect E Struct Rep Online. 2008 May 24;64(Pt 6):m836. doi: 10.1107/S1600536808015183.
7
Di-μ-chlorido-bis-{[4-amino-3,5-bis-(2-pyrid-yl)-4H-1,2,4-triazole-κN]chloridomercury(II)}.二-μ-氯代-双-{[4-氨基-3,5-双-(2-吡啶基)-4H-1,2,4-三唑-κN]氯化汞(II)}
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1180. doi: 10.1107/S1600536811029886. Epub 2011 Aug 2.
8
A second monoclinic polymorph of di-μ-chlorido-bis-(chlorido{2-[(4-ethyl-phen-yl)imino-meth-yl]pyridine-κ²N,N'}copper(II)).二-μ-氯代-双-(氯代{2-[(4-乙基-苯基)亚氨基-甲基]吡啶-κ²N,N'}铜(II))的第二种单斜多晶型物。
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m920-1. doi: 10.1107/S1600536812026347. Epub 2012 Jun 16.
9
catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ⁴N,N',N'',N''')mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido].链状聚[[(联苯甲酰双{[(吡啶-2-基)亚甲基]腙}-κ⁴N,N',N'',N''')汞(II)]-μ-氯代-[二氯汞(II)]-μ-氯代]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m903-4. doi: 10.1107/S1600536812025718. Epub 2012 Jun 13.
10
Crystal structure of di-μ-chlorido-bis-(chlorido-{,-diethyl--[(pyridin-2-yl-κ)methyl-idene]benzene-1,4-di-amine-κ}mercury(II)).二-μ-氯代-双-(氯代-{,-二乙基--[(吡啶-2-基-κ)亚甲基]苯-1,4-二胺-κ}汞(II))的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 May 5;73(Pt 6):809-812. doi: 10.1107/S2056989017005874. eCollection 2017 Jun 1.

引用本文的文献

1
Bis(2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolato-κ(2)N,O)zinc methanol disolvate.双（2-{[（9H-芴-2-基）亚甲基]氨基}-苯酚根-κ(2)N,O）锌甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m504-5. doi: 10.1107/S160053681201272X. Epub 2012 Mar 31.
2
Bis(2-amino-1,3-benzothia-zole-κN)dichloridozinc(II) ethanol hemisolvate.双（2-氨基-1,3-苯并噻唑-κN）二氯锌（II）乙醇半溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m178-9. doi: 10.1107/S1600536812001560. Epub 2012 Jan 21.

本文引用的文献

1
[Benz-yl(2-pyridyl-methyl-idene)amine]-dichloridomercury(II).[苄基（2-吡啶基亚甲基）胺]-二氯化汞（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1251. doi: 10.1107/S1600536810035889.
2
Dichlorido[N,N-diethyl-N'-(2-pyridyl-methyl-ene)ethane-1,2-diamine]mercury(II).二氯[N,N-二乙基-N'-(2-吡啶基亚甲基)乙烷-1,2-二胺]汞(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m124. doi: 10.1107/S1600536810000103.
3
Syntheses and structures of blue-luminescent mercury(II) complexes with 2,6-bis(imino)pyridyl ligands.
蓝色发光汞（II）配合物的合成与结构研究，配体为 2,6-双（亚氨基）吡啶。
Inorg Chem. 2009 Jul 6;48(13):6034-43. doi: 10.1021/ic900339u.
4
"Turn-on" fluorescent sensor for Hg2+ via displacement approach.通过置换法实现的汞离子“开启型”荧光传感器。
Inorg Chem. 2008 Jun 16;47(12):5169-76. doi: 10.1021/ic702494s. Epub 2008 May 15.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
Interaction of 2-(2'-pyridyl)benzimidazolyl derivative ligands with group 12 metal ions: coordination, structures and luminescence.2-(2'-吡啶基)苯并咪唑基衍生物配体与第12族金属离子的相互作用：配位、结构与发光
Dalton Trans. 2006 Dec 28(48):5675-82. doi: 10.1039/b604047k. Epub 2006 Aug 21.