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[苄基（2-吡啶基亚甲基）胺]-二氯化汞（II）

[Benz-yl(2-pyridyl-methyl-idene)amine]-dichloridomercury(II).

作者信息

Kim Young-Inn, Kang Sung Kwon

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1251. doi: 10.1107/S1600536810035889.

DOI:10.1107/S1600536810035889
PMID:21587400
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983418/
Abstract

The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra-hedral geometry being coordinated by two Cl anions and by two N atoms of the benz-yl(2-pyridyl-methyl-ene)amine ligand. The Cl-Hg-Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, inter-molecular π-π inter-actions [centroid-centroid distance = 3.793 (3) Å] between the aromatic rings link the mol-ecules into zigzag chains extending along [010].

摘要

在标题配合物[HgCl₂(C₁₃H₁₂N₂)]中，Hg(II)离子采用扭曲的四面体几何构型，由两个Cl⁻阴离子以及苄基(2 - 吡啶基亚甲基)胺配体的两个N原子配位。Cl - Hg - Cl平面相对于螯合环的平均平面扭转了70.1 (1)°。在晶体结构中，芳环之间的分子间π - π相互作用[质心 - 质心距离 = 3.793 (3) Å]将分子连接成沿[010]方向延伸的锯齿链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/984d/2983418/f3c374accc22/e-66-m1251-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/984d/2983418/9c874fe99481/e-66-m1251-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/984d/2983418/f3c374accc22/e-66-m1251-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/984d/2983418/9c874fe99481/e-66-m1251-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/984d/2983418/f3c374accc22/e-66-m1251-fig2.jpg

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