Starosta Wojciech, Leciejewicz Janusz
Institute of Nuclear Chemistry and Technology, ul.Dorodna 16, 03-195 Warszawa, Poland.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 23;66(Pt 2):m192. doi: 10.1107/S1600536810002199.
In the title structure, Pb(C(5)H(3)N(2)O(2))(2), the Pb(II) ion is six-coordinated by two pyridazine-3-carboxyl-ate ligands via N and O atoms, with the carboxyl-ato O atoms acting as bidentate and bridging adjacent Pb(II) ions, giving rise to catenated mol-ecular ribbons propagating along the a-axis direction. The ribbons are connected by C-H⋯O hydrogen bonds and van der Waals inter-actions.
在标题结构[Pb(C₅H₃N₂O₂)₂]ₙ中,Pb(II)离子通过N和O原子与两个哒嗪-3-羧酸酯配体形成六配位,其中羧基氧原子作为双齿配体并桥连相邻的Pb(II)离子,从而形成沿a轴方向延伸的连环分子带。这些分子带通过C-H⋯O氢键和范德华相互作用相连。