• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[(莲叶桐碱-κN,O)铅(II)]-二-μ-氯]

catena-Poly[[(liriodenine-κN,O)lead(II)]-di-μ-chlorido].

作者信息

Qin Yan-Tao, Tao Lu, He Tian-Jing, Liu Yan-Cheng, Chen Zhen-Feng

机构信息

Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m29. doi: 10.1107/S1600536809051381.

DOI:10.1107/S1600536809051381
PMID:21579928
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980232/
Abstract

The title compound, PbCl(2)(C(17)H(9)NO(3)), was synthesized by the hydro-thermal reaction of PbCl(2) and liriodenine. The lead(II) atom has a distorted octa-hedral environment made up of the O and N atoms of the liriodenine ligand [Pb-O 2.666 (4) Å, Pb-N 2.587 (5) Å, O-Pb-N 61.78 (14)°] and four bridging chloro ligands, which link the complex mol-ecules into infinite chains along the a axis. Both crystallographically independent chloro-bridges are asymmetric, so that the Pb atom participates in two short [2.6872 (18) and 2.7952 (18) Å] and two noticeably longer Pb-Cl bonds [2.9626 (18) and 3.031 (2) Å].

摘要

标题化合物[PbCl₂(C₁₇H₉NO₃)]ₙ是通过PbCl₂与鹅掌楸碱的水热反应合成的。铅(II)原子具有由鹅掌楸碱配体的O和N原子构成的扭曲八面体环境[Pb - O 2.666(4) Å，Pb - N 2.587(5) Å，O - Pb - N 61.78(14)°]以及四个桥连氯配体，这些配体将配合物分子沿a轴连接成无限长链。两个晶体学独立的氯桥均不对称，因此Pb原子参与形成两个短的[2.6872(18)和2.7952(18) Å]以及两个明显更长的Pb - Cl键[2.9626(18)和3.031(2) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/093a/2980232/82a3d717ec62/e-66-00m29-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/093a/2980232/82a3d717ec62/e-66-00m29-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/093a/2980232/82a3d717ec62/e-66-00m29-fig1.jpg

相似文献

1
catena-Poly[[(liriodenine-κN,O)lead(II)]-di-μ-chlorido].链状聚[[(莲叶桐碱-κN,O)铅(II)]-二-μ-氯]
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m29. doi: 10.1107/S1600536809051381.
2
catena-Poly[[[triaqua-copper(II)]-μ-2,2'-bipyridine-3,3'-dicarboxyl-ato-κN,N':O] monohydrate].链状聚[[[三水合铜（II）]-μ-2,2'-联吡啶-3,3'-二羧酸根-κN,N':O]一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1710-1. doi: 10.1107/S1600536811046423. Epub 2011 Nov 9.
3
catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[bis-(1-ethyl-1H-imidazole-κN)cadmium]].链状聚[[双-(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[双-(1-乙基-1H-咪唑-κN)镉]]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1850-1. doi: 10.1107/S160053681104894X. Epub 2011 Nov 30.
4
catena-Poly[potassium-di-μ-aqua-μ-4-(5-tetra-zolio)pyridine].链状聚[二水合钾-μ-4-(5-四唑基)吡啶]
Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):m671. doi: 10.1107/S1600536809018649.
5
catena-Poly[[(acetato-κO,O')(methanol-κO)cadmium(II)]-μ-[1,2-bis-(1H-benzimid-azol-2-yl)ethane]-κN:N-[(acetato-κO,O')(methanol-κO)cadmium(II)]-di-μ-chlorido].链状聚[[(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - μ - [1,2 - 双-(1H - 苯并咪唑 - 2 - 基)乙烷] - κN:N - [(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - 二 - μ - 氯化物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):m578. doi: 10.1107/S1600536810014753.
6
catena-Poly[[(5,5'-dimethyl- 2,2'-bipyridine-κN,N')cadmium(II)]-di-μ-chlorido].链状聚[[(5,5'-二甲基-2,2'-联吡啶-κN,N')镉(II)]-二-μ-氯]
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1233. doi: 10.1107/S1600536808027657.
7
catena-Poly[[[aqua-tris-(pyridine-κN)nickel(II)]-μ-2,3,5,6-tetra-chloro-benzene-1,4-dicarboxyl-ato-κO:O] pyridine monosolvate].链状聚[[[水合三（吡啶-κN）镍（II）]-μ-2,3,5,6-四氯苯-1,4-二羧酸根-κO:O]吡啶单溶剂合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):m1618. doi: 10.1107/S1600536810045794.
8
catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua-chloridocadmate)-di-μ-chlorido]].链状聚[2-甲基-1H-咪唑-3-鎓[(水合氯化镉)-二-μ-氯]]
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1584. doi: 10.1107/S1600536811042905. Epub 2011 Oct 22.
9
catena-Poly[[bis[quinazolin-4(3H)-one-κN]cadmium(II)]-di-μ-chlorido].链状聚[[双[喹唑啉-4(3H)-酮-κN]镉(II)]-二-μ-氯]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):m1457. doi: 10.1107/S1600536810041590.
10
catena-Poly[[chloridomercury(II)]-μ-1,4-diaza-bicyclo-[2.2.2]octane-κN:N'-[chlorido-mercury(II)]-di-μ-chlorido].链状聚[[氯化汞（II）]-μ-1,4-二氮杂双环-[2.2.2]辛烷-κN:N'-[氯化汞（II）]-二-μ-氯]
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 31;65(Pt 11):m1477-8. doi: 10.1107/S1600536809043839.

本文引用的文献

1
Potential new inorganic antitumour agents from combining the anticancer traditional Chinese medicine (TCM) liriodenine with metal ions, and DNA binding studies.通过将抗癌中药莲叶桐碱与金属离子结合开发潜在新型无机抗肿瘤药物及DNA结合研究
Dalton Trans. 2009 Jan 14(2):262-72. doi: 10.1039/b813363h. Epub 2008 Nov 19.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.