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链状聚[[双-(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[(1-乙基-1H-咪唑-κN)镉]-二-μ-氯代-[双-(1-乙基-1H-咪唑-κN)镉]]

catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[bis-(1-ethyl-1H-imidazole-κN)cadmium]].

作者信息

Xu Qian, Zhu Run-Qiang

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1850-1. doi: 10.1107/S160053681104894X. Epub 2011 Nov 30.

Abstract

The asymmetric unit of the crystal structure of the title compound, Cd(2)Cl(4)(C(5)H(8)N(2))(3), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely distorted fivefold coordination by four Cl atoms and one N atom from a 1-ethyl-1H-imidazole ligand. Adjacent Cd(II) cations are inter-connected alternately by pairs of chloride bridges, generating an infinite step-like chain along the a axis. One ethyl group of the 1-ethyl-1H-imidazole ligand is disordered over two sets of sites with a 0.668 (13):0.332 (13) site-occupancy ratio.

摘要

标题化合物[Cd₂Cl₄(C₅H₈N₂)₃]ₙ的晶体结构不对称单元包含两个Cd(II)阳离子、三个1-乙基-1H-咪唑配体和四个Cl⁻阴离子。两个Cd(II)原子具有相当不同的配位环境:一个通过来自两个1-乙基-1H-咪唑配体的四个Cl原子和两个N原子呈八面体配位,另一个通过来自一个1-乙基-1H-咪唑配体的四个Cl原子和一个N原子处于严重扭曲的五重配位。相邻的Cd(II)阳离子通过成对的氯桥交替互连,沿a轴生成无限的阶梯状链。1-乙基-1H-咪唑配体的一个乙基在两组位置上无序,占位比为0.668 (13):0.332 (13)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e70/3238745/d6d58375baac/e-67-m1850-fig1.jpg

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