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链状聚[[三甲基锡(IV)]-μ-2-甲基苯甲酸根-κO:O']

catena-Poly[[trimethyltin(IV)]-μ-2-methylbenzoato-κO:O'].

作者信息

Danish Muhammad, Saleem Iram, Ahmad Nazir, Starosta Wojciech, Leciejewicz Janusz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m4. doi: 10.1107/S1600536809051587.

DOI:10.1107/S1600536809051587
PMID:21579938
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980210/
Abstract

The polymeric structure of the title compound, Sn(CH(3))(3)(C(8)H(7)O(2)), is composed of zigzag chains in which the tin(IV) atoms, coordinated by three methyl groups, are bridged by toluene-2-carboxyl-ate ligands via their O atoms. A slightly distorted trigonal-bipyramidal SnC(3)O(2) coordination geometry arises for the metal, with the O atoms in the axial sites. Weak C-H⋯O hydrogen bonds help to stabilize the packing.

摘要

标题化合物Sn(CH(3))(3)(C(8)H(7)O(2))的聚合结构由锯齿链组成，其中由三个甲基配位的锡(IV)原子通过其O原子被甲苯-2-羧酸酯配体桥连。金属呈现出略微扭曲的三角双锥SnC(3)O(2)配位几何构型，O原子位于轴向位置。弱的C-H⋯O氢键有助于稳定堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c39/2980210/c18fa8a8627c/e-66-000m4-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c39/2980210/a40c8091e788/e-66-000m4-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c39/2980210/c18fa8a8627c/e-66-000m4-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c39/2980210/a40c8091e788/e-66-000m4-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c39/2980210/c18fa8a8627c/e-66-000m4-fig2.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):m609-10. doi: 10.1107/S1600536809015475.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m137. doi: 10.1107/S1600536810000498.