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链状聚[[三甲基锡(IV)]-μ-环己-3-烯-1-羧酸根]

catena-Poly[[trimethyl-tin(IV)]-μ-cyclo-hex-3-ene-1-carboxyl-ato].

作者信息

Ren Yun, Zhang Rufen, Shi Yang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):m92. doi: 10.1107/S1600536809054403.

DOI:10.1107/S1600536809054403
PMID:21579982
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980015/
Abstract

The title compound, Sn(CH(3))(3)(C(7)H(9)O(2)), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H⋯O hydrogen bond.

摘要

标题化合物[Sn(CH₃)₃(C₇H₉O₂)]ₙ形成了一个平行于[010]方向延伸的锯齿形链状结构。锡原子处于略微扭曲的三角双锥配位环境中，两个羧酸根氧原子位于轴向，三个甲基位于赤道位置。环己烯环具有扭曲的半船式构象。存在分子内C-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633b/2980015/a42f58531a4d/e-66-00m92-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633b/2980015/01b1c3301c25/e-66-00m92-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633b/2980015/a42f58531a4d/e-66-00m92-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633b/2980015/01b1c3301c25/e-66-00m92-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633b/2980015/a42f58531a4d/e-66-00m92-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Reactions of 2-mercaptobenzoic acid with divalent alkaline earth metal ions: synthesis, spectral studies, and single-crystal X-ray structures of calcium, strontium, and barium complexes of 2,2'-dithiobis(benzoic acid).2-巯基苯甲酸与二价碱土金属离子的反应：2,2'-二硫代双（苯甲酸）钙、锶和钡配合物的合成、光谱研究及单晶X射线结构
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