水合双（2,3-二甲基-4-氧代-4H-吡啶并[1,2-a]嘧啶-9-醇根）镍（II）
Aqua-bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II).
作者信息
Zhang Huaihong, Sun Yu, Chen Xiaodan, Yu Fei, Zou Zhihong
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m5. doi: 10.1107/S1600536809051563.
Abstract
In the crystal structure of the mononuclear title complex, [Ni(C(10)H(9)N(2)O(2))(2)(H(2)O)], the Ni(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from 2,3-dimethyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and one O atom from a water mol-ecule. O-H⋯O hydrogen bonds between the coordinated water mol-ecule and the ligand connect adjacent mol-ecules, forming a ribbon parallel to the b axis.
摘要
在单核标题配合物[Ni(C₁₀H₉N₂O₂)₂(H₂O)]的晶体结构中，Ni(II)离子通过来自2,3-二甲基-4-氧代吡啶并[1,2-a]嘧啶-9-醇盐配体的两个N原子和两个O原子以及来自一个水分子的一个O原子，以扭曲的四方锥几何构型进行五配位。配位水分子与配体之间的O—H⋯O氢键连接相邻分子，形成平行于b轴的带状结构。
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本文引用的文献
1
Aqua-bis(2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato)zinc(II) monohydrate.一水合双（2-甲基-4-氧代吡啶并[1,2-a]嘧啶-9-醇根）锌（II）
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2
Diaqua-bis[3-(2-hydroxy-ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κN,O]manganese(II).二水合双[3-(2-羟乙基)-2-甲基-4-氧代吡啶并[1,2-a]嘧啶-9-醇根合-κN,O]锰(II)
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