双[μ-3-(2-羟乙基)-2-甲基-4-氧代-4H-吡啶并[1,2-a]嘧啶-9-醇根合-κN,O:O]双[水合氯铜(II)]
Bis[μ-3-(2-hydroxy-ethyl)-2-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato-κN,O:O]bis[aquachloridocopper(II)].
作者信息
Deng Ying, Li Zhong-Shu, Sun Bai-Wang
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1262. doi: 10.1107/S1600536808028687.
In the dinuclear centrosymmetric copper(II) title compound, [Cu(2)(C(11)H(11)N(2)O(2))(2)Cl(2)(H(2)O)(2)], each Cu(II) ion has a slightly distorted trigonal-bipyramidal geometry and is coordinated by one N and one O atom from one 3-(2-hydroxy-ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligand, another O atom from the second ligand, one water mol-ecule and one Cl atom. The crystal structure involves inter-molecular C-H⋯Cl, O-H⋯Cl and O-H⋯O hydrogen bonds.
在双核中心对称的铜（II）标题化合物[Cu₂(C₁₁H₁₁N₂O₂)₂Cl₂(H₂O)₂]中，每个铜（II）离子具有轻微扭曲的三角双锥几何构型，并且由来自一个3-(2-羟乙基)-2-甲基-4-氧代吡啶并[1,2-a]嘧啶-9-醇盐配体的一个氮原子和一个氧原子、来自第二个配体的另一个氧原子、一个水分子和一个氯原子配位。晶体结构涉及分子间的C-H⋯Cl、O-H⋯Cl和O-H⋯O氢键。
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