Wang Cui-Juan, Zhou Xian-Li, Zhang Bing-Jun
Department of Chemistry and Chemical Engineering, School of Bioengineering, SouthWest JiaoTong University, Chengdu, Sichuan 610031, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m50. doi: 10.1107/S1600536809052659.
In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa-hedral geometry arising from the O,N,N',O'-tetra-dentate Schiff base ligand, an azide ion and a water mol-ecule. In the crystal, inter-molecular O-H⋯(O,O) and O-H⋯N hydrogen bonds and π-π inter-actions [centroid-centroid separation = 3.5535 (13) Å] link the mol-ecules into chains.
在标题配合物[Mn(C₂₈H₁₈N₂O₂)(N₃)(H₂O)]中，Mn(III)离子呈现出一种扭曲的面式MnO₃N₃八面体几何构型，这是由O,N,N',O'-四齿席夫碱配体、一个叠氮离子和一个水分子导致的。在晶体中，分子间的O—H⋯(O,O)和O—H⋯N氢键以及π-π相互作用[质心-质心间距 = 3.5535 (13) Å]将分子连接成链。
