水合叠氮基-{2,2'-[邻亚苯基双(次氮基甲基亚基)]二酚根合}锰(III)半水合物
Aqua-azido-{2,2'-[o-phenylenebis(nitrilo-methyl-idyne)]diphenolato}manganese(III) hemihydrate.
作者信息
Zhang Xiutang, Wei Peihai, Li Bin, Wu Chunyong, Hu Bo
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m707. doi: 10.1107/S1600536809020200.
In the title compound, [Mn(C(20)H(14)N(2)O(2))(N(3))(H(2)O)]·0.5H(2)O, the Mn(III) ion is chelated by the N,N',O,O'-tetra-dentate Schiff base ligand and further coordinated by one azide ion and one water mol-ecule in trans positions, resulting in a distorted fac-MnN(3)O(3) octa-hedral arrangement. The O atom of the uncoordinated water mol-ecule lies on a crystallographic twofold axis. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds help to establish the packing.
在标题化合物[Mn(C₂₀H₁₄N₂O₂)(N₃)(H₂O)]·0.5H₂O中，Mn(III)离子由N,N',O,O'-四齿席夫碱配体螯合，并进一步由一个叠氮离子和一个水分子在反位配位，形成扭曲的面式-MnN₃O₃八面体构型。未配位水分子的O原子位于晶体学二重轴上。在晶体中，O—H⋯O和O—H⋯N氢键有助于形成堆积结构。
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