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四-双（μ(2)-3,4-二甲氧基-苯基-乙酸根）-κO,O':O';κO:O:O';κO:O';κO:O'-双-[(3,4-二甲氧基-苯基-乙酸根-κO,O')(1,10-菲咯啉-κN,N)铥(III)]

Tetra-kis(μ(2)-3,4-dimethoxy-phenyl-acetato)-κO,O':O';κO:O:O';κO:O';κO:O'-bis-[(3,4-dimethoxy-phenyl-acetato-κO,O')(1,10-phenanthroline-κN,N)thulium(III)].

作者信息

Liu Jia-Lu, Li Hua-Qiong, Zhao Guo-Liang

机构信息

Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m9. doi: 10.1107/S1600536809051435.

DOI:10.1107/S1600536809051435
PMID:21579980
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979998/
Abstract

In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging and bridging tridentate modes.

摘要

在标题为中心对称双核配合物[Tm₂(C₁₀H₁₁O₄)₆(C₁₂H₈N₂)₂]中，独特的Tm(III)离子通过七个O原子和两个N原子与五个3,4-二甲氧基苯乙酸（DMPA）配体及一个双螯合的1,10-菲咯啉（phen）配体配位，形成一个扭曲的三帽三角棱柱环境。DMPA配体以双螯合、桥联和桥连三齿模式配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd19/2979998/811bfbd06dc1/e-66-000m9-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd19/2979998/811bfbd06dc1/e-66-000m9-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd19/2979998/811bfbd06dc1/e-66-000m9-fig1.jpg

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本文引用的文献

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Poly[diaqua-penta-kis(μ(4)-benzene-1,2-dicarboxyl-ato)(μ(3)-benzene-1,2-dicarboxyl-ato)tetra-thulium(III)].聚[二水合-五（μ(4)-苯-1,2-二羧基-ato）（μ(3)-苯-1,2-二羧基-ato）四铥（III）]
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