2-{[(4-甲氧基-苯基)二甲基-甲硅烷基]甲基}异吲哚啉-1,3-二酮
2-{[(4-Methoxy-phen-yl)dimethyl-silyl]meth-yl}isoindoline-1,3-dione.
作者信息
Guzei Ilia A, Spencer Lara C, Zakai Uzma I
机构信息
Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, Wisconsin 53706, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):o219-20. doi: 10.1107/S1600536809054129.
In the course of our studies of silicon-containing anti-cancer compounds, the title compound, C(18)H(19)NO(3)Si, was synthesized. The mol-ecular geometry including bond distances and angles involving the Si atoms are typical. Torsion angles associated with the isoindoline ring and the silyl group [C-N-C(methyl-ene)-Si = 90.5 (2) and -93.1 (2)°] indicate that there is no inter-action between the O and Si atoms despite silicon's high affinity for oxygen.
在我们对含硅抗癌化合物的研究过程中，合成了标题化合物C(18)H(19)NO(3)Si。包括涉及硅原子的键长和键角在内的分子几何结构是典型的。与异吲哚啉环和硅烷基相关的扭转角[C-N-C(亚甲基)-Si = 90.5 (2) 和 -93.1 (2)°]表明，尽管硅对氧有很高的亲和力，但氧原子和硅原子之间没有相互作用。
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