Mandal Tanmay, Samanta Sampak, Broker Grant A, Zhao Cong-Gui, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):o99. doi: 10.1107/S160053680905260X.
In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra-molecular chains mediated by O-H⋯O hydrogen bonds, which propagate in the a-axis direction. A C-H⋯O inter-action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components.
在标题化合物C₁₄H₂₁FNO₆P中，围绕中心P-C键存在交错构象，其中羰基和羟基占据对角相对的位置。晶体结构具有由O-H⋯O氢键介导的超分子链，这些链沿a轴方向延伸。C-H⋯O相互作用巩固了这些链。对于其中一个异丙基的无序问题，两种组分的占有率为0.60 (2):0.40 (2)，已得到解决。
