Yin Qi, Gan Xin
College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):m369. doi: 10.1107/S1600536810007312.
In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra-hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements.
在标题单核铜（I）配合物[Cu(C₁₈H₁₅P)(C₄₁H₃₉P₃)]BF₄中，阳离子具有基本的刚性核心结构，让人联想到金刚石的骨架。金属原子由四个磷原子以扭曲的四面体几何构型配位，这种扭曲源于苯基的空间位阻。阴离子在两个位置上无序分布，占有率之比为0.524 (17):0.476 (17)。阳离子和阴离子在晶体中紧密堆积，呈六方密堆积排列。
